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Abstract The photolytic reactions of iron thiocarbonato complexes CpFe(CO)2SC(Y)Y′R [Y = Y′ = O; R = 2-C6H4Cl (1), 4-C6H4Cl (2); Y = S, Y′ = O; R = C6H4F (3), Y = Y′ = S; R = Ph (4)] with EPh3 (E = P, As, Sb) are performed. Monosubstituted complexes… Click to show full abstract
Abstract The photolytic reactions of iron thiocarbonato complexes CpFe(CO)2SC(Y)Y′R [Y = Y′ = O; R = 2-C6H4Cl (1), 4-C6H4Cl (2); Y = S, Y′ = O; R = C6H4F (3), Y = Y′ = S; R = Ph (4)] with EPh3 (E = P, As, Sb) are performed. Monosubstituted complexes of the general formula CpFe(CO)(EPh3)SC(Y)Y′R [Y = Y′ = O; R = 2-C6H4Cl (5), 4-C6H4Cl (6); Y = S, Y′ = O; R = C6H4F (7), Y = Y′ = S; R = Ph (8); E = P (a), As (b), Sb (c)] have been isolated and characterized by spectroscopic analysis (UV–Vis, IR, 1H, 31P NMR) and elemental analysis. The molecular structures of CpFe(CO)(PPh3)SCO2-2-C6H4Cl (5a) and its dicarbonyl parent CpFe(CO)2SCO2-2-C6H4Cl (1) have been determined by single crystal X-ray crystallographic studies.
Journal Title: Polyhedron
Year Published: 2017
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