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Abstract Herein is reported the synthesis of an anionic gold complex bearing two charged hydrido carboranyl phosphine ligands. The compound is fully characterized by multinuclear NMR spectroscopy, high resolution mass… Click to show full abstract
Abstract Herein is reported the synthesis of an anionic gold complex bearing two charged hydrido carboranyl phosphine ligands. The compound is fully characterized by multinuclear NMR spectroscopy, high resolution mass spectrometry, as well as a single crystal X-ray diffraction study. In addition, we probe this compound’s ability to catalyze the hydroamination of alkynes and compare its behavior to a related highly active catalyst supported by a perchlorinated carboranyl phosphine.
Keywords:
carboranyl;
hydrido carboranyl;
charged hydrido;
carboranyl phosphine;
synthesis anionic
Journal Title: Polyhedron
Year Published: 2018
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Journal Title: Polyhedron
Year Published: 2018
Link to full text (if available)
Share on Social Media: Sign Up to like & get
recommendations!