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Fabrication of semi-conductive natural rubber nanocomposites with low copper nanoparticle contents

Abstract In this study, copper nanoparticles (CNPs) were applied to obtain optimized mechanical and electrical properties of copper nanoparticles/natural rubber composites cured through sulfur vulcanization. Moreover, the effect of both… Click to show full abstract

Abstract In this study, copper nanoparticles (CNPs) were applied to obtain optimized mechanical and electrical properties of copper nanoparticles/natural rubber composites cured through sulfur vulcanization. Moreover, the effect of both conventional and efficient curing systems, in presence of copper nanoparticles or without CNPs, on these mentioned properties was also compared. For this purpose, compounds including different contents of copper nanoparticles were prepared under the same processing condition considered for each sample preparation. The samples were cured by means of compression molding at constant temperature/pressure and specific time duration. The efficient cured samples containing 0.074 vol% of CNPs possessed the highest electrical conductivity (∼0.014 S m −1 ) at a percolation threshold and showed tensile strength around 12.79 MPa among different samples. SEM and TEM data revealed that homogenous dispersion and distribution were attained for the efficient cured samples reinforced with a considerably low amount of CNPs.

Keywords: natural rubber; copper; semi conductive; copper nanoparticles; fabrication semi

Journal Title: Polymer
Year Published: 2017

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