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Sub-critical gas-assisted processing using CO2 foaming to enhance the exfoliation of graphene in polypropylene + graphene nanocomposites

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Abstract Polypropylene (PP) and graphene nanoparticles (GNPs) were mixed in a twin-screw extruder equipped with a simple CO 2 injection unit consisting of a standard gas cylinder, a regulator, a… Click to show full abstract

Abstract Polypropylene (PP) and graphene nanoparticles (GNPs) were mixed in a twin-screw extruder equipped with a simple CO 2 injection unit consisting of a standard gas cylinder, a regulator, a valve, and a metal hose. Nanocomposites were produced with a 0.5% by weight GNP loading level. The addition of CO 2 into the melt at pressures below the supercritical point allowed for foaming to occur within the barrel of the extruder and upon exiting from the die. Foaming introduces an equibiaxial flow on the surface of the expanding bubbles. This extensional flow imparts a stress greater than the shear case alone, aiding in the breakup of GNP agglomerates. Samples processed with sub-critical CO 2 showed increased exfoliation and dispersion as observed via electron microscopy, thermal analysis, Raman spectroscopy, and X-ray diffraction. This sub-critical gas-assisted processing (SGAP) method was introduced as an alternative to supercritical fluid-assisted processing.

Keywords: polypropylene graphene; graphene; assisted processing; sub critical; critical gas

Journal Title: Polymer
Year Published: 2017

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