Abstract The development of new green alternatives for anticorrosive and antifouling coatings is essential for the conservation of the environment. A coating with more than one functionality, for example both… Click to show full abstract
Abstract The development of new green alternatives for anticorrosive and antifouling coatings is essential for the conservation of the environment. A coating with more than one functionality, for example both anticorrosion and antifouling is of great interest for cost reduction and for improved coating efficiency. In this work, the multifunctional effect of propolis within a silicone matrix coating was evaluated. Fourier transform infrared (FTIR) and 13 C nuclear magnetic resonance ( 13 C NMR) analyses confirmed the presence of several compounds with active properties ( e.g. polyphenols, cinnamic acid, ferulic acid, and diterpenes). The addition of propolis and TiO 2 increased the thermal stability of the final coating while keeping the water contact angle of the silicone, near to 98°. Electrochemical impedance spectroscopy (EIS) experiments showed that the presence of propolis increased the anticorrosive properties, and bacterial experiments showed decreased adhesion of the gram-positive bacteria Staphylococcus aureus (ATCC 6538). Marine experiments also showed the excellent antifouling efficiency of the paint containing propolis over 11 months. The use of a natural pigment allied to a solvent free resin contributes to the formulation of more environmentally friendly paints.
               
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