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Hierarchical ZSM-5 zeolite synthesized via dry gel conversion-steam assisted crystallization process and its application in aromatization of methanol

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Abstract Hierarchical ZSM-5 zeolites were prepared by “Dry Gel Conversion-Steam Assisted Crystallization” (DGC-SAC) procedure without the involvement of additional template. Moreover, the formation mechanism and feather of mesopores were summarized.… Click to show full abstract

Abstract Hierarchical ZSM-5 zeolites were prepared by “Dry Gel Conversion-Steam Assisted Crystallization” (DGC-SAC) procedure without the involvement of additional template. Moreover, the formation mechanism and feather of mesopores were summarized. Nanoscale Kirkendall effect was existed in the growth of zeolite crystals under high SiO2/TPA+ ratio, which was responsible for the production of intra-crystal mesopores. However, small ZSM-5 nano-crystallites, with the average diameter of

Keywords: steam assisted; conversion steam; dry gel; hierarchical zsm; gel conversion; zsm

Journal Title: Powder Technology
Year Published: 2018

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