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Improved corrosion protection of waterborne epoxy/graphene coating by combining non-covalent and covalent bonds

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Abstract High-efficient anti-corrosive epoxy coating, containing homogeneously dispersive graphene (Gr), has been achieved by combining non-covalent and covalent bonds. Tannic acid (TA) has been used as intercalators to disperse Gr… Click to show full abstract

Abstract High-efficient anti-corrosive epoxy coating, containing homogeneously dispersive graphene (Gr), has been achieved by combining non-covalent and covalent bonds. Tannic acid (TA) has been used as intercalators to disperse Gr in water via π − π non-covalent bond to form Gr-TA hybrids. Consequently, γ-(2,3-epoxypropoxy)propytrimethoxysilane was used to modify the surface of Gr-TA via covalent bond to enhance the interactions between Gr-TA and epoxy. The corrosion resistance properties of the composite Gr-TA/epoxy coatings were tested by electrochemical experiment and salt spray test. The results showed that anti-corrosion properties of Gr-TA-KH560/epoxy composite coatings were hugely enhanced compared with those of the Gr-TA/epoxy and pure epoxy.

Keywords: covalent bonds; graphene; non covalent; covalent covalent; corrosion; combining non

Journal Title: Reactive and Functional Polymers
Year Published: 2019

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