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Synthesis and characterization of paramagnetic isotropic glycine manganese chloride single crystal with various dopant concentrations

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Abstract Single crystals of α and γ glycine manganese chloride (GMC) were prepared using four dopant concentrations of MnCl2 in the molecular formula (C2H5NO2)1−x(MnCl2)x, where [x = 0.005, 0.02, 0.04, 0.05]. The… Click to show full abstract

Abstract Single crystals of α and γ glycine manganese chloride (GMC) were prepared using four dopant concentrations of MnCl2 in the molecular formula (C2H5NO2)1−x(MnCl2)x, where [x = 0.005, 0.02, 0.04, 0.05]. The crystals showed: nonlinear optical (NLO) activity, high transparency in UV–Vis. range of electromagnetic radiation, ferroelectric and dielectric characteristic with dielectric loss less than unity at high applied frequency. In addition, electron paramagnetic resonance were done for GMC4 crystal and shows a broad isotropic Lorentzian line (with g = 1.9692, ΔH = 416.2 G). The crystals possessed paramagnetic properties and were recommended in manufacturing of mini magnets.

Keywords: glycine manganese; crystal; isotropic; manganese chloride; dopant concentrations

Journal Title: Results in Physics
Year Published: 2019

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