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Anisotropic behavior of grain boundary diffusion in hot-deformed Nd-Fe-B magnet

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Abstract Grain boundary diffusion process using Nd70Cu30 was applied to the c-plane and ab-plane of hot-deformed Nd-Fe-B magnet. The coercivity was increased from 1.38 T to 2.44 and 2.20 T for the… Click to show full abstract

Abstract Grain boundary diffusion process using Nd70Cu30 was applied to the c-plane and ab-plane of hot-deformed Nd-Fe-B magnet. The coercivity was increased from 1.38 T to 2.44 and 2.20 T for the ab-plane and c-plane diffused specimens, respectively. The corresponding diffusion depth characterized by Cu content in the magnet was about 4.5 and 2.3 mm for the two specimens. Hierarchical coupling between “river-like” Nd-rich phase on the powder flake surface in micron-scale with the diffusion channels at the grain boundaries and triple junctions of the matrix grains in nano-scale is the fundamental cause of the anisotropic grain boundary diffusion behavior.

Keywords: grain boundary; diffusion; hot deformed; deformed magnet; boundary diffusion

Journal Title: Scripta Materialia
Year Published: 2017

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