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Coercivity enhancement of hot-deformed Nd-Fe-B magnets by the eutectic grain boundary diffusion process using Nd62Dy20Al18 alloy

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Abstract The eutectic grain boundary diffusion process was applied to a 2-mm-thick hot-deformed Nd-Fe-B magnets using Nd62Dy20Al18 alloy as a diffusion source, realizing the coercivity enhancement from 0.91 T to 2.75 T… Click to show full abstract

Abstract The eutectic grain boundary diffusion process was applied to a 2-mm-thick hot-deformed Nd-Fe-B magnets using Nd62Dy20Al18 alloy as a diffusion source, realizing the coercivity enhancement from 0.91 T to 2.75 T with relatively small remanence deterioration from 1.50 T to 1.30 T. In contrast, the conventional grain boundary diffusion process using Dy-vapor resulted in the degradation of coercivity as the grains are catastrophically coarsened at the processing temperature of 900 °C. Scanning transmission electron microscopy showed the formation of Dy-rich shell at the sides of the Nd2Fe14B grains and the diffusion of Al into the Nd2Fe14B grains, explaining the significant improvement in coercivity.

Keywords: diffusion process; grain boundary; diffusion; boundary diffusion; coercivity

Journal Title: Scripta Materialia
Year Published: 2017

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