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First hexagonal close packed high-entropy alloy with outstanding stability under extreme conditions and electrocatalytic activity for methanol oxidation

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Abstract High-entropy alloys containing 5 and 6 platinum group metals have been prepared by thermal decomposition of single-source precursors non requiring high temperature or mechanical alloying. The prepared Ir 0.19… Click to show full abstract

Abstract High-entropy alloys containing 5 and 6 platinum group metals have been prepared by thermal decomposition of single-source precursors non requiring high temperature or mechanical alloying. The prepared Ir 0.19 Os 0.22 Re 0.21 Rh 0.20 Ru 0.19 alloy is the first example of a single-phase hexagonal high-entropy alloy. Heat treatment up to 1500 K and compression up to 45 GPa do not result in phase changes, a record temperature and pressure stability for a single-phase high-entropy alloy. The alloys show pronounced electrocatalytic activity in methanol oxidation, which opens a route for the use of high-entropy alloys as materials for sustainable energy conversion.

Keywords: entropy; entropy alloy; electrocatalytic activity; high entropy; activity methanol

Journal Title: Scripta Materialia
Year Published: 2017

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