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Thermoelectric properties and cost optimization of spark plasma sintered n-type Si0.9Ge0.1 - Mg2Si nanocomposites

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Abstract We report on thermoelectric properties of low Ge content n -type Si 0.9 Ge 0.1 –Mg 2 Si nanocomposite. Introduction of the Mg 2 Si phase into a SiGe… Click to show full abstract

Abstract We report on thermoelectric properties of low Ge content n -type Si 0.9 Ge 0.1 –Mg 2 Si nanocomposite. Introduction of the Mg 2 Si phase into a SiGe matrix resulted in a dramatic drop of the lattice thermal conductivity beyond the previously reported lowest limit for SiGe alloys due to intensification of phonon scattering on SiGe–Mg 2 Si grain boundaries. For a sample doped with 1 at.% of Mg 2 Si, the peak value of thermoelectric figure of merit ZT reached ~ 0.8 at 800 °C. Sintered nanocomposites still exhibit high thermoelectric performance while being almost two times cheaper than Si 0.8 Ge 0.2 .

Keywords: properties cost; cost optimization; thermoelectric properties; plasma sintered; optimization spark; spark plasma

Journal Title: Scripta Materialia
Year Published: 2018

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