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Enhanced thermoelectric performance of Te-doped skutterudite with nano-micro-porous architecture

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Abstract Te-doped Co4Sb11.5Te0.5 materials with nano to micro sized pores are fabricated tactfully by annealing the nano-Co4Sb11.5Te0.5/Co4Sb11.5Te0.5 composites. The annealed samples present a dramatically reduced thermal conductivity due to the… Click to show full abstract

Abstract Te-doped Co4Sb11.5Te0.5 materials with nano to micro sized pores are fabricated tactfully by annealing the nano-Co4Sb11.5Te0.5/Co4Sb11.5Te0.5 composites. The annealed samples present a dramatically reduced thermal conductivity due to the abundant scattering of phonons in a wide wavelength range by the obtained all-scale porous architecture. Meanwhile, the Seebeck coefficient is enhanced for the annealed samples due to the lower carrier concentration. The sample annealed 100 h exhibits an enhanced dimensionless figure of merit of 1.2 at 800 K, increased by 33.7% as compared with that of the dense sample.

Keywords: nano micro; co4sb11 5te0; enhanced thermoelectric; thermoelectric performance; porous architecture

Journal Title: Scripta Materialia
Year Published: 2019

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