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Correlation between microstructure of TiO2-anatase precursor and lithium storage properties of hydrothermally synthesized TiO2-B

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Abstract TiO2-B nanobelts have been synthesized by hydrothermal route using TiO2-anatase precursors with different microstructure. The decrease in average size of starting product improves the degree of TiO2-B crystallinity and… Click to show full abstract

Abstract TiO2-B nanobelts have been synthesized by hydrothermal route using TiO2-anatase precursors with different microstructure. The decrease in average size of starting product improves the degree of TiO2-B crystallinity and increases the surface area. Both of them strongly influence on the electrochemical performance of as-prepared TiO2-B: the capacity of 203 mAh g−1 is still maintained after 35 cycles, with a degradation of 0.25% per cycle for material synthesized using TiO2-anatase phase with a particle size of 25 nm. Oppositely, the samples obtained from larger particles show poorer lithium storage with a worse capacity retention.

Keywords: correlation microstructure; lithium storage; tio2 anatase

Journal Title: Scripta Materialia
Year Published: 2019

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