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In situ natural ageing of Al-Cu-(Mg) alloys: The effect of In and Sn on the very early stages of decomposition

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Abstract The influence of trace elements (0.01 at.% In/Sn) on the decomposition process of Al-Cu-(Mg) alloys during the very early stages of natural ageing has been investigated in situ by small… Click to show full abstract

Abstract The influence of trace elements (0.01 at.% In/Sn) on the decomposition process of Al-Cu-(Mg) alloys during the very early stages of natural ageing has been investigated in situ by small angle X-ray scattering supported with differential scanning calorimetry and hardness measurements. In the binary Al-Cu alloy quenched-in vacancies are bound to In or Sn, resulting in a suppressed Cu clustering process. In Al-Cu-Mg room temperature hardening occurs much faster due to Mg entering the clusters. However, the influence of In or Sn is negligible. Cu and Mg possibly form complexes with quenched-in vacancies before they can reach a trace element atom.

Keywords: alloys effect; decomposition; early stages; situ natural; natural ageing; ageing alloys

Journal Title: Scripta Materialia
Year Published: 2019

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