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Insight into the scavenger effect of LiF on extinction of a carboxylate group for mid-infrared transparent Y2O3−MgO nanocomposite

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Abstract Y2O3−MgO nanocomposite is introduced for infrared transparent ceramics due to its superior optical and mechanical characteristics. However, severe optical scattering and unnecessary absorption in the near- and mid-infrared regions… Click to show full abstract

Abstract Y2O3−MgO nanocomposite is introduced for infrared transparent ceramics due to its superior optical and mechanical characteristics. However, severe optical scattering and unnecessary absorption in the near- and mid-infrared regions restrict the applications of this material. Here, a broad mid-infrared transparent Y2O3−MgO nanocomposite is achieved for the first time through low temperature sintering using an LiF additive. The influence of LiF is successfully demonstrated on the mid-infrared transparency of the as-sintered and post-annealed nanocomposites. Spectroscopic analysis are also performed, and primary absorption factors of the Y2O3−MgO transparent ceramics are revealed. This study is a step toward designing widely utilized transparent ceramics.

Keywords: mid infrared; y2o3 mgo; mgo nanocomposite; infrared transparent

Journal Title: Scripta Materialia
Year Published: 2020

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