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Synthesis and crystallization kinetics of Y2CaAl4SiO12 garnet-type glass-ceramic

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Abstract Y2CaAl4SiO12 garnet-type glass-ceramic was obtained by heat-treatment of the bulk glass with corresponding composition, which fabricated by aerodynamic levitation coupled with a laser heating system. The crystallization kinetics of… Click to show full abstract

Abstract Y2CaAl4SiO12 garnet-type glass-ceramic was obtained by heat-treatment of the bulk glass with corresponding composition, which fabricated by aerodynamic levitation coupled with a laser heating system. The crystallization kinetics of the glass was investigated via Differential Scanning Calorimetry (DSC). The effects of heat-treatment temperature on the phase, microstructure, mechanical and optical properties of the Y2CaAl4SiO12 garnet-type glass-ceramic were also systemically studied. The crystallization mechanism of this Y2CaAl4SiO12 glass is three-dimensional growth followed with surface and inner nucleation. With the increasing of heat-treatment temperature, the density and hardness increased, while transparency declined as a result of rapid grain growth.

Keywords: y2caal4sio12 garnet; glass; garnet type; type glass; glass ceramic

Journal Title: Scripta Materialia
Year Published: 2020

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