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Revisiting ω phase embrittlement in metastable β titanium alloys: Role of elemental partitioning

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Abstract The role of elemental partitioning between β and ω phase in embrittling an originally ductile ω-containing Ti–12Mo (wt.%) model alloy was studied using transmission electron microscopy and atom probe… Click to show full abstract

Abstract The role of elemental partitioning between β and ω phase in embrittling an originally ductile ω-containing Ti–12Mo (wt.%) model alloy was studied using transmission electron microscopy and atom probe tomography. It is revealed that the embrittlement of this alloy already occurs after aging at 400 °C for as short as 10 min, when the size, inter-particle spacing and volume fraction of the ω particles remain almost unchanged. The origin of the aging-induced embrittlement is attributed to the significant rejection of Mo (>5 at.%) from the ω particles during aging, which leads to remarkable increase in the shear modulus (>30 GPa) of the ω particles, promoting intense plastic flow localization and facilitating crack nucleation prior to macroscopic yielding.

Keywords: elemental partitioning; role elemental; revisiting phase; embrittlement

Journal Title: Scripta Materialia
Year Published: 2021

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