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Fabrication of Fe2O3/g-C3N4@N-TiO2 photocatalyst nanotube arrays that promote bisphenol A photodegradation under simulated sunlight irradiation

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Abstract Bisphenol A (BPA) is a typical endocrine-disrupting chemical. Because BPA cannot be completely degraded by traditional sewage treatment plants, alternative technology is urgently needed. Photocatalytic degradation using sunlight is… Click to show full abstract

Abstract Bisphenol A (BPA) is a typical endocrine-disrupting chemical. Because BPA cannot be completely degraded by traditional sewage treatment plants, alternative technology is urgently needed. Photocatalytic degradation using sunlight is attractive due to its efficiency, low cost, and environmental friendliness. In this study, a photocatalyst, Fe2O3/g-C3N4@N-TNA, was synthesized by doping with N and loading Fe2O3 and graphitic carbon nitride (g-C3N4) onto TiO2 nanotube arrays (TNAs). The morphology and structure of this catalyst were investigated. Fe2O3/g-C3N4@N-TNA has a band gap of 2.15 eV. This photocatalyst can completely degrade BPA (4.5 mg/L) in 40 min and follows pseudofirst order kinetics. Furthermore, hydroxyl radicals ( OH) are the key to BPA degradation. The OH concentration generated by this photocatalytic system reached 0.4 μmol/L after 60 min under simulated sunlight irradiation. The photocatalyst Fe2O3/g-C3N4@N-TNA could be an alternative for BPA degradation.

Keywords: photocatalyst; simulated sunlight; nanotube arrays; fe2o3 c3n4; c3n4

Journal Title: Separation and Purification Technology
Year Published: 2020

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