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Magnetic and thermal behavior of a family of compositionally related zero-dimensional fluorides

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Abstract The mild hydrothermal crystal growth technique has been leveraged to synthesize four new zero-dimensional transition metal fluorides. Their structures were determined by single crystal X-ray diffraction and confirmed by… Click to show full abstract

Abstract The mild hydrothermal crystal growth technique has been leveraged to synthesize four new zero-dimensional transition metal fluorides. Their structures were determined by single crystal X-ray diffraction and confirmed by powder X-ray diffraction. The thermal, optical, and magnetic properties were investigated and the presence of thermal polymorphism and antiferromagnetism were observed. In addition, the potential application of these materials as precursors for advanced functional materials was explored.

Keywords: thermal behavior; family compositionally; zero dimensional; magnetic thermal; behavior family; compositionally related

Journal Title: Solid State Sciences
Year Published: 2018

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