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Reconsideration of the gallium nitride: Dual functionality as an electron transporter and transparent conductor for recyclable polymer solar cell substrate applications

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Abstract Herein, we report the dual functionality of a single n-type gallium nitride (n-GaN) layer as an electron transporter and transparent conductor, which has applications in reusable organic solar cells.… Click to show full abstract

Abstract Herein, we report the dual functionality of a single n-type gallium nitride (n-GaN) layer as an electron transporter and transparent conductor, which has applications in reusable organic solar cells. After silicon doping with an optimized electron concentration, thin-film layer of GaN showed exceptional electrical properties including charge carrier mobility of 161 cm2 V−1s−1, electrical conductivity of 1.4ⅹ106 S cm−1, and sheet resistance of 11.1 Ω cm−2. Organic solar cells based on n-GaN exhibited power conversion efficiency comparable to those based on a conventional ITO/ZnO bilayered cathode. Furthermore, the n-GaN substrates exhibited reusability; due to excellent chemical stability of n-GaN, the reconstructed organic solar cells maintained their initial performance after the substrates were recycled. We suggest a new type of reusable n-GaN cathode layer featuring an integrated electron transporting layer and transparent electrode.

Keywords: electron transporter; solar; dual functionality; transporter transparent; electron; gallium nitride

Journal Title: Solar Energy Materials and Solar Cells
Year Published: 2019

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