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Mechanism of polar catastrophe cancelling induced by charge compensation for epitaxy γ-Fe2O3 film on MgO(001) substrate: A theoretical investigation

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Abstract The interface of γ-Fe2O3/MgO(001) film have revived considerable attention. Polar catastrophe at the interface of γ-Fe2O3/MgO(001) film was investigated and an attempt to investigate the interface structure and growth… Click to show full abstract

Abstract The interface of γ-Fe2O3/MgO(001) film have revived considerable attention. Polar catastrophe at the interface of γ-Fe2O3/MgO(001) film was investigated and an attempt to investigate the interface structure and growth mode of γ-Fe2O3/MgO(001) was given. The results show that the stoichiometric γ-Fe2O3 with tetragonal space group of P41212 should grow on MgO(001) in the [100] or [010] direction. The charge compensation by modifying the stoichiometry in the interface layer can not only stabilize the polar surface, but also give a reasonable interpretation for why the saturation magnetization (Ms) values of the very thin γ-Fe2O3/MgO films are larger than the bulk value of γ-Fe2O3 in experimental studies. This study may widen the application of maghemite especially the γ-Fe2O3/MgO film.

Keywords: mgo 001; fe2o3 mgo; charge compensation; polar catastrophe; film; fe2o3

Journal Title: Superlattices and Microstructures
Year Published: 2018

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