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Evaluation of the structure, optical and electronic properties of Zn1-xRuxO thin films via mercaptopurine modified sol-gel spin coating approach

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Abstract Highly transparent and conducting Zn1-xRuxO films have been developed via mercaptopurine modified sol-gel spin coating approach as an efficient alternative for indium tin oxide electrodes. The crystalline structure and… Click to show full abstract

Abstract Highly transparent and conducting Zn1-xRuxO films have been developed via mercaptopurine modified sol-gel spin coating approach as an efficient alternative for indium tin oxide electrodes. The crystalline structure and surface topography of the Zn1-xRuxO films have been explored by X-ray diffraction and SEM. The optical spectroscopy was monitored by ellipsometry. The data was fitted by Forouhi- Bloomer model and harmonic oscillator model. The increase of Ru amount in ZnO causes a decrease of the optical bandgap achieving the lowest value at 1 wt% of Ru dopant. The free carriers’ concentration for this film reached to 1021 cm−3. The Zn0.99Ru0.01O film showed high transparency exceeds 95% and outstanding resistivity of 10−5 Ω cm along the whole visible spectrum region. These unique characteristics may open the road for developing novel, cost-effective and highly transparent and conducting metal oxide electrodes for the future of optoelectronic applications.

Keywords: sol gel; mercaptopurine modified; xruxo; via mercaptopurine; zn1 xruxo; modified sol

Journal Title: Superlattices and Microstructures
Year Published: 2019

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