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Bi as an antisurfactant in heteroepitaxial growth of Co/Au(111) multilayers

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Abstract The influence of additional surface species of Bi atoms on the structural and magnetic properties of Co/Au (111) multilayers deposited using molecular beam epitaxy has been studied by reflection… Click to show full abstract

Abstract The influence of additional surface species of Bi atoms on the structural and magnetic properties of Co/Au (111) multilayers deposited using molecular beam epitaxy has been studied by reflection high-energy electron diffraction (RHEED), X-ray diffraction (XRD), grazing incidence X-ray reflectivity (XRR) and a vibrating sample magnetometer (VSM). The initial deposition of a Bi submonolayer onto the Au (111) buffer layer prior to the deposition of a Co/Au multilayer changed the heteroepitaxial growth of the Co/Au multilayer. The RHEED results proved that Bi reduced the layer-by-layer growth of the Co/Au multilayer. The results of XRD and XRR revealed that interfaces of the Co/Au multilayers with the predeposited Bi layer were rougher than those without Bi. These results indicated that Bi worked as an antisurfactant to enhance the three-dimensional island growth of the Co/Au multilayer. The coercive force and remnant magnetization of the Co/Au multilayers was enhanced by the predeposition of Bi. However, when the Co layer thickness was greater than 15 A, the magnetic anisotropy energy of the Co/Au multilayers decreased due to the deposition of the Bi layer.

Keywords: growth; heteroepitaxial growth; 111 multilayers; layer; growth multilayer; antisurfactant heteroepitaxial

Journal Title: Solid State Communications
Year Published: 2021

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