LAUSR

Abstract Effect of Chloride, Nitrate, Bromide and Iodide anions of Potassium on the critical micellar concentration of a non-ionic surfactant Pluronic F108 was determined by using UV–visible spectroscopy. Dye-micellization method was adopted using the diazo dye, Trypan blue. The influence of the above mentioned salts on the surfactant structures, concentration and working experimental condition at the cmc were evaluated and discussed. The micellization was observed to occur at lower concentration in presence of the above salts. The influence of the above salts on cmc was characterized using UV- spectrophotometry, fluorimetry, dynamic light scattering, fluorescence lifetime and cloud point studies. It was noticed that the salts affect the aggregation process consistent with the Hofmeister series with the Chloride, the Nitrate, the Bromide and the Iodide ions coming in decreasing order. Trypan blue has been used, probably for first time as a probe for UV- spectroscopy and fluorimetry analysis in surfactant system.