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Copper-catalyzed reductive borylations on water

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Abstract In this paper, we established copper catalyzed reductive borylation of terminal alkynes and diboron on water in the presence of amine. Moderate conditions enabled selective borylations of vinyl-substituted phenylacetylenes… Click to show full abstract

Abstract In this paper, we established copper catalyzed reductive borylation of terminal alkynes and diboron on water in the presence of amine. Moderate conditions enabled selective borylations of vinyl-substituted phenylacetylenes to undergo the borylation at a C C triple bond. The Cu catalyst can be recycled for seven times.

Keywords: catalyzed reductive; borylations water; reductive borylations; copper catalyzed

Journal Title: Tetrahedron
Year Published: 2017

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