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Abstract Chiral, ionic C 2 -symmetric binaphthyl fluorophores with amphipathic property can emit circularly polarized luminescence (CPL) in the near-UV region when dissolved in either water or methanol. Despite the… Click to show full abstract
Abstract Chiral, ionic C 2 -symmetric binaphthyl fluorophores with amphipathic property can emit circularly polarized luminescence (CPL) in the near-UV region when dissolved in either water or methanol. Despite the same axial chirality ( R or S ) of the binaphthyl units, the open- and closed-style fluorophores induced sign inversion of CPL and circular dichroism (CD) signals in water. The dihedral angle of the binaphthyl C 2 -axis appears to determine the signs of CPL and CD signals even in water.
Keywords:
binaphthyl fluorophores;
open closed;
binaphthyl;
water;
circularly polarized;
polarized luminescence
Journal Title: Tetrahedron
Year Published: 2017
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Journal Title: Tetrahedron
Year Published: 2017
Link to full text (if available)
Share on Social Media: Sign Up to like & get
recommendations!