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A new synthesis of highly functionalized cyclohexenes via a vinylogous Ferrier-Petasis cyclization reaction

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Abstract Research on the O→C rearrangement reaction shows that alkoxydienes undergo a smooth rearrangement in a vinylogous manner with a catalytic amount of titanium (IV) chloride, which leads to highly… Click to show full abstract

Abstract Research on the O→C rearrangement reaction shows that alkoxydienes undergo a smooth rearrangement in a vinylogous manner with a catalytic amount of titanium (IV) chloride, which leads to highly substituted cyclohexenes a particularly useful starting material in the synthesis of cyclohexane containing products.

Keywords: new synthesis; functionalized cyclohexenes; reaction; synthesis highly; highly functionalized; synthesis

Journal Title: Tetrahedron
Year Published: 2017

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