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Abstract A highly reactive intermediate N-sulfonyl acetylketenimine was generated from an ynone-participated CuAAC/ring-opening method. Its unique structure allowed it to react with aryl carboxylic acids to give N-aroylsulfonamides via a… Click to show full abstract
Abstract A highly reactive intermediate N-sulfonyl acetylketenimine was generated from an ynone-participated CuAAC/ring-opening method. Its unique structure allowed it to react with aryl carboxylic acids to give N-aroylsulfonamides via a novel Mumm-type rearrangement.
Keywords:
highly reactive;
acetylketenimine highly;
intermediate synthesis;
synthesis aroylsulfonamides;
reactive intermediate;
sulfonyl acetylketenimine
Journal Title: Tetrahedron
Year Published: 2019
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Journal Title: Tetrahedron
Year Published: 2019
Link to full text (if available)
Share on Social Media: Sign Up to like & get
recommendations!