Abstract Regioselective hydroxysulfenylation of unactivated C C double bonds was reported. Using FeBr3-bpy as the catalyst, Na2S2O8 as the oxidant, and sulfonyl hydrazides as the sulfenyl sources, hydroxysulfenylation of unfunctionalized… Click to show full abstract
Abstract Regioselective hydroxysulfenylation of unactivated C C double bonds was reported. Using FeBr3-bpy as the catalyst, Na2S2O8 as the oxidant, and sulfonyl hydrazides as the sulfenyl sources, hydroxysulfenylation of unfunctionalized olefins proceeded readily, giving a variety of β-hydroxysulfides in moderate to good isolated yields.
Keywords:
hydroxysulfenylation;
regioselective hydroxysulfenylation;
catalyzed regioselective;
febr3 catalyzed;
sulfonyl hydrazides;
hydroxysulfenylation allylsulfonamides
Journal Title: Tetrahedron
Year Published: 2019
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Journal Title: Tetrahedron
Year Published: 2019
Link to full text (if available)
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recommendations!