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Abstract Dinickel complexes promote stoichiometric Pauson–Khand reactions of enynes and CO (g). However, catalytic turnover is precluded by the strong binding of CO to the Ni2 active site. This article… Click to show full abstract
Abstract Dinickel complexes promote stoichiometric Pauson–Khand reactions of enynes and CO (g). However, catalytic turnover is precluded by the strong binding of CO to the Ni2 active site. This article describes the use of M(CO)x reagents as stoichiometric CO precursors in Ni2-catalyzed carbonylation reactions. As part of these studies, well-defined heterotrinuclear Ni2Fe, Ni2Co, and Ni2Mn carbonyl clusters are synthesized using the [NDI]Ni2 platform as a template (NDI = naphthyridine–diimine).
Keywords:
carbonylation reactions;
reactions using;
dinickel catalyzed;
catalyzed carbonylation;
carbonyl
Journal Title: Tetrahedron
Year Published: 2019
Link to full text (if available)
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Journal Title: Tetrahedron
Year Published: 2019
Link to full text (if available)
Share on Social Media: Sign Up to like & get
recommendations!