Photo by traumhaendler from unsplash
Abstract Perylene diimide and its various derivatives tend to form stable anion radicals, which can usually form a variety of aggregates with special properties. Herein, we reported synthesis and properties… Click to show full abstract
Abstract Perylene diimide and its various derivatives tend to form stable anion radicals, which can usually form a variety of aggregates with special properties. Herein, we reported synthesis and properties of the benzo[ghi]perylene trimide and its anion radical π-bonded dimer. The dimer exhibited high stable in solid status and in most organic solvents, but conversion of L-type π-bonded dimer to face to face type π-bonded dimer or π-stacked oligomer occurs in dimethyl formamide solution. The temperature and crystallization influenced the π-bonded length in the dimer and the partial memory can be reserved and probed in solution at room temperature.
Journal Title: Tetrahedron
Year Published: 2019
Link to full text (if available)
Share on Social Media: Sign Up to like & get
recommendations!