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ABSTRACT The reductive intermolecular coupling of phthalimides with esters by low-valent titanium gave five-, six-, and seven-membered cyclized products as α-hydroxyketones and their further reduced ketones. The obtained cyclized products… Click to show full abstract
ABSTRACT The reductive intermolecular coupling of phthalimides with esters by low-valent titanium gave five-, six-, and seven-membered cyclized products as α-hydroxyketones and their further reduced ketones. The obtained cyclized products were transformed to alkylideneisoindolin-1-ones. The reductive intermolecular coupling of phthalimides with ketones by low-valent titanium also gave five-, six-, and seven-membered cyclized products as alkylideneisoindolin-1-ones in one step.
Keywords:
phthalimides esters;
low valent;
coupling phthalimides;
valent titanium;
ketones low
Journal Title: Tetrahedron
Year Published: 2020
Link to full text (if available)
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Journal Title: Tetrahedron
Year Published: 2020
Link to full text (if available)
Share on Social Media: Sign Up to like & get
recommendations!