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Abstract Aryl migration reactions of C-3 aryl substituted pyrrolidinoindoline compounds to provide highly conjugated C-2 aryl indole compounds have been discovered. The developed reactions have a wide substrate scope and… Click to show full abstract
Abstract Aryl migration reactions of C-3 aryl substituted pyrrolidinoindoline compounds to provide highly conjugated C-2 aryl indole compounds have been discovered. The developed reactions have a wide substrate scope and proceed in high yield under simple acidic conditions. A unique cationic cyclopropane intermediate as the transition state is proposed.
Keywords:
aryl substituted;
migration reaction;
acid mediated;
aryl migration;
mediated aryl
Journal Title: Tetrahedron Letters
Year Published: 2017
Link to full text (if available)
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Journal Title: Tetrahedron Letters
Year Published: 2017
Link to full text (if available)
Share on Social Media: Sign Up to like & get
recommendations!