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Green and mild laccase-catalyzed aerobic oxidative coupling of benzenediol derivatives with various sodium benzenesulfinates

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The oxidative coupling reaction between hydroquinone or catechols and various sodium benzenesulfinates was investigated using the laccase from Trametes versicolor, in the presence of O2 in a phosphate buffer solution… Click to show full abstract

The oxidative coupling reaction between hydroquinone or catechols and various sodium benzenesulfinates was investigated using the laccase from Trametes versicolor, in the presence of O2 in a phosphate buffer solution at room temperature to afford sulfonyl benzenediols in 75–95% yield.

Keywords: sodium benzenesulfinates; laccase; various sodium; oxidative coupling; green mild

Journal Title: Tetrahedron Letters
Year Published: 2017

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