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Abstract Eumelanin-supported palladium (Pd) nanoparticle (NP) catalysts was found to exhibit excellent catalytic activities with high turnover number (TON, 2000) and turnover frequency (TOF, 1000 h −1 ) for Suzuki cross… Click to show full abstract
Abstract Eumelanin-supported palladium (Pd) nanoparticle (NP) catalysts was found to exhibit excellent catalytic activities with high turnover number (TON, 2000) and turnover frequency (TOF, 1000 h −1 ) for Suzuki cross coupling reaction of aryl chlorides in water. We propose that the amphiphilic property of the eumelanin support helps Pd NPs to catalyse the C–C coupling reaction in water through hydrophobic effect.
Keywords:
water;
coupling reaction;
reaction;
palladium nanoparticle;
reaction aryl;
aryl chlorides
Journal Title: Tetrahedron Letters
Year Published: 2017
Link to full text (if available)
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Journal Title: Tetrahedron Letters
Year Published: 2017
Link to full text (if available)
Share on Social Media: Sign Up to like & get
recommendations!