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Visible-light-promoted synthesis of diaryl sulfides under air

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Abstract A convergent, organocatalytic visible-light-mediated process for the synthesis of diaryl sulfides has been developed. A broad range of aryl thiols reacted with various aryl diazonium salts in the presence… Click to show full abstract

Abstract A convergent, organocatalytic visible-light-mediated process for the synthesis of diaryl sulfides has been developed. A broad range of aryl thiols reacted with various aryl diazonium salts in the presence of eosin Y under air atmosphere to afford the desired diaryl sulfides in high yields. This novel and environmentally friendly method provides an alternative route to established synthetic approaches.

Keywords: synthesis diaryl; diaryl sulfides; visible light; air; diaryl

Journal Title: Tetrahedron Letters
Year Published: 2017

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