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Facile synthesis of dimeric aza-BODIPY analogues from electron-deficient bislactams and their intriguing optical and electrochemical properties

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Abstract Electron-deficient bislactams, isoindigo and benzodipyrrolidone, were converted into dimeric aza-BODIPY analogues by a Schiff base forming reaction. These novel aza-BODIPY analogues exhibited bathochromically-shifted absorption and anodic shifts of the… Click to show full abstract

Abstract Electron-deficient bislactams, isoindigo and benzodipyrrolidone, were converted into dimeric aza-BODIPY analogues by a Schiff base forming reaction. These novel aza-BODIPY analogues exhibited bathochromically-shifted absorption and anodic shifts of the reduction potentials, implying their potential application as n-type chromophores in optoelectronics.

Keywords: aza bodipy; electron deficient; bodipy analogues; deficient bislactams

Journal Title: Tetrahedron Letters
Year Published: 2017

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