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Abstract A convenient synthetic approach towards previously unknown N- and N,O-silylated α-iminophosphonates bearing fluoroalkyl groups at the imine C atom was developed. The synthetic potential of the compounds was demonstrated… Click to show full abstract
Abstract A convenient synthetic approach towards previously unknown N- and N,O-silylated α-iminophosphonates bearing fluoroalkyl groups at the imine C atom was developed. The synthetic potential of the compounds was demonstrated by their easy functionalization and the straightforward preparation of biorelevant aminophosphonates and free aminophosphonic acids with heterocyclic residues in the α-position.
Keywords:
iminophosphonates novel;
aminophosphonic acids;
reactive synthons;
silylated iminophosphonates;
novel reactive;
preparation
Journal Title: Tetrahedron Letters
Year Published: 2017
Link to full text (if available)
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Journal Title: Tetrahedron Letters
Year Published: 2017
Link to full text (if available)
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recommendations!