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Highly chemoselective reduction of azides to amines by Fe(0) nanoparticles in water at room temperature

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Abstract A highly chemoselective reduction of aryl, heteroaryl, acyl and sulfonyl azides to the corresponding amines has been achieved by Fe(0) nanoparticles in water at room temperature in the absence… Click to show full abstract

Abstract A highly chemoselective reduction of aryl, heteroaryl, acyl and sulfonyl azides to the corresponding amines has been achieved by Fe(0) nanoparticles in water at room temperature in the absence of external hydride source. Several readily reducible functionalities including alkene, alkyne, S-S linkage, OTBDMS remain unaffected during reduction.

Keywords: reduction; nanoparticles water; chemoselective reduction; water room; room temperature; highly chemoselective

Journal Title: Tetrahedron Letters
Year Published: 2017

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