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Direct cross-coupling of aryl alkynyliodines with arylsulfinic acids leading to alkynyl sulfones under catalyst-free conditions

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A facile and efficient one-pot method has been developed for the construction of alkynyl sulfones via direct cross-coupling reaction of aryl alkynyliodines and arylsulfinic acids. The present transformation could be… Click to show full abstract

A facile and efficient one-pot method has been developed for the construction of alkynyl sulfones via direct cross-coupling reaction of aryl alkynyliodines and arylsulfinic acids. The present transformation could be accomplished under catalyst- and additive-free conditions, providing a series of alkynyl sulfones in moderate to good yields with favorable functional group tolerance. (C) 2017 Elsevier Ltd. All rights reserved.

Keywords: direct cross; aryl alkynyliodines; arylsulfinic acids; alkynyliodines arylsulfinic; alkynyl sulfones; cross coupling

Journal Title: Tetrahedron Letters
Year Published: 2017

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