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Abstract A novel and convenient synthetic route for aryl methyl sulfones and β -hydroxysulfones was developed via the radical reaction between sodium sulfinates and di- tert -butyl peroxide (DTBP). Without… Click to show full abstract
Abstract A novel and convenient synthetic route for aryl methyl sulfones and β -hydroxysulfones was developed via the radical reaction between sodium sulfinates and di- tert -butyl peroxide (DTBP). Without any catalysts and additives, the synthetic process could be smoothly carried out to afford the target products in good to excellent yields in H 2 O medium, demonstrating its promising application. In the present system, H 2 O could act not only as a green solvent but also as a reactant.
Keywords:
aryl methyl;
sulfinates tert;
methyl sulfones;
sodium sulfinates;
sulfones hydroxysulfones;
tert butyl
Journal Title: Tetrahedron Letters
Year Published: 2018
Link to full text (if available)
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Journal Title: Tetrahedron Letters
Year Published: 2018
Link to full text (if available)
Share on Social Media: Sign Up to like & get
recommendations!