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Abstract A new nitrosation and oxidation process to synthesize gem -dinitro compounds was accomplished by using nitryl chloride as nitrosation reagent and ozone as oxidizing agent. The main features of… Click to show full abstract
Abstract A new nitrosation and oxidation process to synthesize gem -dinitro compounds was accomplished by using nitryl chloride as nitrosation reagent and ozone as oxidizing agent. The main features of the present protocol include the compatibility to substances with high steric hindrance, high yields and mild reaction conditions. A plausible mechanism involving the formation of an intermediate of gem -nitrosonitro compound by means of single electron transfer was also proposed.
Keywords:
gem;
dinitro compounds;
nitrosation oxidation;
high steric;
nitrosation;
gem dinitro
Journal Title: Tetrahedron Letters
Year Published: 2018
Link to full text (if available)
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Journal Title: Tetrahedron Letters
Year Published: 2018
Link to full text (if available)
Share on Social Media: Sign Up to like & get
recommendations!