Abstract Catalyzed by Ir(dFCF 3 ppy) 2 (dtbbpy)PF 6 , several aroyl methylidenemalonates were synthesized in good to excellent yields via visible light photoredox-catalyzed the oxidative ring-opening of cyclopropenyl carboxylate… Click to show full abstract
Abstract Catalyzed by Ir(dFCF 3 ppy) 2 (dtbbpy)PF 6 , several aroyl methylidenemalonates were synthesized in good to excellent yields via visible light photoredox-catalyzed the oxidative ring-opening of cyclopropenyl carboxylate derivatives. The possible mechanism of oxidative quenching cycle was proposed.
               
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