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[4+2] Annulation of 3-(2,2-diethoxyethyl)-1,3-dicarbonyl compounds with indoles catalyzed by Brønsted acid ionic liquid for the synthesis of carbazoles

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Abstract Various carbazoles were synthesized via [4+2] annulation of 3-(2,2-diethoxyethyl)-1,3-dicarbonyl compounds with indoles. A Bronsted acid ionic liquid, [BPy]HSO4, was proven to be effective catalyst for this reaction. The ionic… Click to show full abstract

Abstract Various carbazoles were synthesized via [4+2] annulation of 3-(2,2-diethoxyethyl)-1,3-dicarbonyl compounds with indoles. A Bronsted acid ionic liquid, [BPy]HSO4, was proven to be effective catalyst for this reaction. The ionic liquid catalyst can be recycled three times without significant loss of its catalytic activity.

Keywords: ionic liquid; liquid; compounds indoles; dicarbonyl compounds; diethoxyethyl dicarbonyl; annulation diethoxyethyl

Journal Title: Tetrahedron Letters
Year Published: 2018

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