Photo by joshuafernandez from unsplash
Abstract A series of thiadiazole-based dithiafulvalene (DTF) derivatives has been synthesized in moderate yields via iodine-mediated oxidative vinylic C(sp2)–H sulfenylation with mercapto-thiadiazoles. The formation of C(sp2)–S bond was confirmed and… Click to show full abstract
Abstract A series of thiadiazole-based dithiafulvalene (DTF) derivatives has been synthesized in moderate yields via iodine-mediated oxidative vinylic C(sp2)–H sulfenylation with mercapto-thiadiazoles. The formation of C(sp2)–S bond was confirmed and characterized by NMR and single crystal X-ray diffraction studies. This new protocol is simple and effective for preparation DTF containing thiadiazole group.
Keywords:
iodine mediated;
based dithiafulvalene;
elemental iodine;
thiadiazole based
Journal Title: Tetrahedron Letters
Year Published: 2019
Link to full text (if available)
Share on Social Media: Sign Up to like & get
recommendations!
Journal Title: Tetrahedron Letters
Year Published: 2019
Link to full text (if available)
Share on Social Media: Sign Up to like & get
recommendations!