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An amphiphilic supramolecular polymer: Construction, self-assembly and pH-responsive behavior in water

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Abstract A novel amphiphilic supramolecular polymer (ASP) with rigid linear main chain has been constructed by the co-assembly of a rigid amphiphilic monomer and cucurbit[8]uril (CB[8]) in water, driven by… Click to show full abstract

Abstract A novel amphiphilic supramolecular polymer (ASP) with rigid linear main chain has been constructed by the co-assembly of a rigid amphiphilic monomer and cucurbit[8]uril (CB[8]) in water, driven by CB[8]-based host-guest interactions. The ASP could further self-assemble into well-defined architectures including nanotubes and 2D films, depending on its concentration. Moreover, pH-responsive behavior of the ASP was also observed.

Keywords: supramolecular polymer; amphiphilic supramolecular; responsive behavior; water

Journal Title: Tetrahedron Letters
Year Published: 2019

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