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Synthesis of novel 6-piperidin-1-ylpyrimidine-2,4-diamine 3-oxide substituted calix[4]arene as a highly selective and sensitive fluorescent sensor for Cu2+ in aqueous samples

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Abstract In this study, we designed and synthesized a novel sensitive fluorescent sensor for Cu2+ cation by attaching two minoxidil molecules at the lower-rim of calix[4]arene annulus via the formation… Click to show full abstract

Abstract In this study, we designed and synthesized a novel sensitive fluorescent sensor for Cu2+ cation by attaching two minoxidil molecules at the lower-rim of calix[4]arene annulus via the formation of two urea linkages. This chemosensor can selectively recognize Cu2+ in EtOH containing 5% H2O through a significant decline in fluorescence emission. The structure of the target molecule was determined by HRMS, 1H NMR, 13C NMR and FT-IR.

Keywords: fluorescent sensor; sensor cu2; sensitive fluorescent; calix arene

Journal Title: Tetrahedron Letters
Year Published: 2020

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