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Abstract Iodine/TBHP/DMSO mediated oxidative rearrangement of 3-styrylquinoxalin-2(1H)-one led to the formation of 3-aroylquinoxalin-2(1H)-ones in good to high yields via Kornblum oxidation. This methodology proceeds under mild conditions via oxidative aryl… Click to show full abstract
Abstract Iodine/TBHP/DMSO mediated oxidative rearrangement of 3-styrylquinoxalin-2(1H)-one led to the formation of 3-aroylquinoxalin-2(1H)-ones in good to high yields via Kornblum oxidation. This methodology proceeds under mild conditions via oxidative aryl migration, followed by C C bond cleavage and does not make use of any metal.
Keywords:
tbhp dmso;
dmso mediated;
oxidative rearrangement
Journal Title: Tetrahedron Letters
Year Published: 2021
Link to full text (if available)
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Journal Title: Tetrahedron Letters
Year Published: 2021
Link to full text (if available)
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recommendations!