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What is the dopant concentration in polycrystalline thin-film Cu(In,Ga)Se2?

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We compare the dopant concentration of polycrystalline Cu(In,Ga)Se2 thin film absorbers derived from Hall and capacitance-voltage measurements. Although both measurements techniques appear to be reliable, dopant concentrations determined by capacitance-voltage… Click to show full abstract

We compare the dopant concentration of polycrystalline Cu(In,Ga)Se2 thin film absorbers derived from Hall and capacitance-voltage measurements. Although both measurements techniques appear to be reliable, dopant concentrations determined by capacitance-voltage analysis are significantly lower and vary with probing depth into the absorber. The doping profiles and differences between both measurement techniques are consistent with Cd in-diffusion from the CdS buffer layer during solar cell fabrication. Different doping profiles obtained after a variation of the CdS deposition process support this scenario.

Keywords: dopant concentration; se2; thin film; concentration polycrystalline

Journal Title: Thin Solid Films
Year Published: 2017

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